|
|
(2S)-4-(prop-1-en-1-yl)-2,3-dihydro-1H-pyrrole-2-carboxylate <=> (2S)-4-propylidene-2,3-dihydropyrrole-2-carboxylate + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21206
|
|
|
|
D-erythro-D-gluco-octose_8-phosphate + ATP <=> D-erythro-D-gluco-octose_alpha-1,8-bisphosphate + ADP + H+
|
2.7.1
|
–
|
| |
MetaCyc:
RXN-15793
|
|
|
|
aldehydo-octose_8-phosphate <=> D-erythro-D-gluco-octose_8-phosphate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15792
|
|
|
|
S-adenosyl-L-methionine + S-demethyllincomycin <=> S-adenosyl-L-homocysteine + lincomycin_A + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-21216
|
|
|
|
N-demethyllincomycin-S-cysteine_conjugate + S-adenosyl-L-methionine <=> lincomycin-S-cysteine_conjugate + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-12852
|
|
|
|
keto-D-fructose_6-phosphate <=> beta-D-fructose_6-phosphate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-14812
|
|
|
|
D-erythro-alpha-D-gluco-octopyranose1-phosphate + GTP + H+ <=> GDP-D-erythro-alpha-D-gluco-octose + diphosphate
|
2.7.7
|
–
|
| |
MetaCyc:
RXN-15795
|
|
|
|
lincomycin-S-cysteine_conjugate + H2O <=> S-demethyllincomycin + L-serine
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21215
|
|
|
|
D-erythro-D-gluco-octose_alpha-1,8-bisphosphate + H2O <=> D-erythro-alpha-D-gluco-octopyranose1-phosphate + phosphate
|
3.1.3
|
–
|
| |
MetaCyc:
RXN-15794
|
|
|
|
4-propyl-L-proline + ATP + H+ <=> (4-propyl-L-prolyl)adenylate + diphosphate
|
2.7.7
|
–
|
| |
MetaCyc:
RXN-21209
|
|
|
|
GDP-D-erythro-alpha-D-gluco-octose <=> GDP-D-alpha-D-lincosamide
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21212
|
|
|
|
(2S)-4-propyl-2,3-dihydro-1H-pyrrole-2-carboxylate + reduced_coenzyme_F420 + H+ <=> 4-propyl-L-proline + coenzyme_F420
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12860
|
|
|
|
keto-D-fructose_6-phosphate + D-ribose_5-phosphate <=> octulose_8-phosphate + D-glyceraldehyde_3-phosphate
|
2.2.1
|
–
|
| |
MetaCyc:
RXN-15790
|
|
|
|
(4-propyl-L-prolyl)-[4-propyl-L-proline-carrier_protein] + ergothioneyl-D-alpha-D-lincosamide <=> ergothioneyl-N-demethyllincomycin + holo-[4-propyl-L-proline-carrier_protein] + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12851
|
|
|
|
octulose_8-phosphate <=> aldehydo-octose_8-phosphate
|
5.3.1
|
–
|
| |
MetaCyc:
RXN-15791
|
|
|
|
S-adenosyl-L-methionine + 3-vinyl-2,3-pyrroline-5-carboxylate <=> S-adenosyl-L-homocysteine + (2S)-4-(prop-1-en-1-yl)-2,3-dihydro-1H-pyrrole-2-carboxylate + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-21205
|
|
|
|
1-(mycothiol-S-yl)-N-demethyllincomycin + H2O <=> N-demethyllincomycin_mercapturate + 1-O-(2-amino-2-deoxy-alpha-D-glucopyranosyl)-1D-myo-inositol
|
3.5.1.115
mycothiol S-conjugate amidase
|
–
|
| |
MetaCyc:
RXN-21214
|
|
|
|
sedoheptulose_7-phosphate + D-ribose_5-phosphate <=> octulose_8-phosphate + D-erythrose_4-phosphate
|
2.2.1
|
–
|
| |
MetaCyc:
RXN-15789
|
|
|
|
(4-propyl-L-prolyl)adenylate + holo-[4-propyl-L-proline-carrier_protein] <=> (4-propyl-L-prolyl)-[4-propyl-L-proline-carrier_protein] + AMP + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21210
|
|
|
|
L-Dopa + O2 <=> H+ + 5-(L-alanin-3-yl)-2-hydroxy-cis,cis-muconate_6-semialdehyde
|
1.13.11.30
stizolobinate synthase
|
–
|
| |
BRENDA:
BR37131
KEGG:
R02076
MetaCyc:
STIZOLOBINATE-SYNTHASE-RXN
|
|
|
|
(2S)-4-propylidene-2,3-dihydropyrrole-2-carboxylate + reduced_coenzyme_F420 <=> (2S)-4-propyl-2,3-dihydro-1H-pyrrole-2-carboxylate + coenzyme_F420
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21207
|
|
|
|
5-(L-alanin-3-yl)-2-hydroxy-cis,cis-muconate_6-semialdehyde <=> 4-[(1Z)-3-carboxy-3-oxoprop-1-en-1-yl]-2,3-dihydro-1H-pyrrole-2-carboxylate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12854
|
|
|
|
GDP-D-alpha-D-lincosamide + ergothioneine <=> ergothioneyl-D-alpha-D-lincosamide + GDP + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21211
|
|
|
|
N-demethyllincomycin_mercapturate + H2O <=> N-demethyllincomycin-S-cysteine_conjugate + acetate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21217
|
|
|
|
4-[(1Z)-3-carboxy-3-oxoprop-1-en-1-yl]-2,3-dihydro-1H-pyrrole-2-carboxylate + H2O <=> 3-vinyl-2,3-pyrroline-5-carboxylate + oxalate + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12859
|
|
|
|
L-tyrosine + H2O2 <=> L-Dopa + H2O
|
1.11.2.6
L-tyrosine peroxygenase
1.14.18.1
tyrosinase
|
–
–
|
| |
BRENDA:
BR53064
KEGG:
R12611
MetaCyc:
RXN-21208
|
|
|
|
ergothioneyl-N-demethyllincomycin + mycothiol <=> ergothioneine + 1-(mycothiol-S-yl)-N-demethyllincomycin
|
not assigned
|
–
|
| |
MetaCyc:
RXN-21213
|
|
